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"Mogwai Fear Satan" is a sixteen-minute-long instrumental, using basic rock instrumentation; guitars, bass, and drums, along with flute. The origin of the song title stems from bassist Dominic Aitchison’s fear of the Devil, due to his Catholic upbringing, which continues to this day as Aitchison is the only religious member of Mogwai

"Mogwai Fear Satan" begins with a guitar melody riff consisting of three chords by Stuart Braithwaite and John Cummings, which is soon joined by bass played by Dominic Aitchison and a frantic drumbeat played by Martin Bulloch, which fades gradually in. The same guitar riff is repeated throughout the song, at times frighteningly distorted. During the quiet parts of the song, in the build up to the explosion of sound and feedback which Mogwai are known for, there is a quiet, haunting flute melody played by Shona Brown over tribal-sounding drums. The song slowly fades out into feedback and noise.